单壁碳纳米管薄膜制备及其光学特性研究

宋秋艳; 陈根祥; 谭晓琳; 田恺

doi:10.7510/jgjs.issn.1001-3806.2014.02.008

单壁碳纳米管薄膜制备及其光学特性研究

1.
北京交通大学光波技术研究所全光网络与现代通信网教育部重点实验室, 北京 100044;
2.
中央民族大学理学院, 北京 100081

作者简介: 宋秋艳（1986- ），女，博士研究生，主要从事非线性光学材料方面的研究。.

通讯作者: 陈根祥, gxchen_bjtu@163.com ;

基金项目:
国家自然科学基金资助项目（61275052）
中图分类号: O484.4

Preparation of single-walled carbon nanotube film and its optical property

1.
Key Laboratory of All Optical Network and Advanced Telecommunication Network of Ministry of Education, Institute of Lightwave Technology, Beijing Jiaotong University, Beijing 100044, China;
2.
School of Science, Minzu University of China, Beijing 100081, China

Corresponding author: CHEN Genxiang, gxchen_bjtu@163.com ;

CLC number: O484.4

摘要: 为了将单壁碳纳米管制成实际可用的光电子器件，采用一种新的梯度升温热亚胺化法来制备单壁碳纳米管/聚酰亚胺薄膜。利用分光光度计测得单壁碳纳米管的质量分数为0.02的单壁碳纳米管/聚酰亚胺薄膜的反射谱、透射谱和吸收谱，得到薄膜线性折射率随波长的变化；拟合Sellmeyer公式，得到单壁碳纳米管/聚酰亚胺薄膜的Sellmeyer参量。利用z扫描技术研究了单壁碳纳米管/聚酰亚胺薄膜的3阶非线性特性。结果表明，单壁碳纳米管/聚酰亚胺薄膜具有很强的饱和吸收特性，其非线性吸收系数为β=-5.3×10-10 cm/W；并且具有较强的自散焦效应，对应的非线性折射系数为γ=-4.1×10-13 cm2/W。单壁碳纳米管/聚酰亚胺薄膜具有较强的非线性光学特性。
- 薄膜 /
- 单壁碳纳米管/聚酰亚胺 /
- 分光光度计 /
- Sellmeyer公式 /
- z扫描 /
- 3阶非线性特性
Abstract: In order to prepare actual optoelectronic devices using single-walled carbon nanotubes, single-walled carbon nanotube/polyimide (SWCNT/PI) film with the single-walled carbon nanotubes in mass fraction of 0.02 was prepared by means of a new gradient temperature-elevating thermal imidization method. The reflectance, transmittance, and absorbance of the film were measured with a spectrophotometer and the linear refractive index variation with wavelength of SWCNT/PI film was obtained. Simultaneously, the Sellmeyer parameters of the SWCNT/PI film were got by fitting the Sellmeyer formula. Then, the third order nonlinear optical property of the SWCNT/PI film was studied by means of z-scanning. The experiments showed that the nonlinear absorption coefficient and the nonlinear refractive coefficient of the film were -5.3×10-9cm/W and -4.1×10-13cm2/W, respectively. The results prove that SWCNT/PI film owns strong nonlinear optical property.
- thin films /
- single-walled carbon nanotube/polyimide /
- spectrophotometer /
- Sellmeyer formula /
- z-scanning /
- third-order nonlinear characteristics

[1]	IJIMA S. Helical microtubules of graphitic carbon [J]. Nature, 1991, 354(6348): 56-58.
[2]	YELLAMPALLI S. Carbon nanotubes: synthesis, characterization, applications [M]. Rijeka,Croatia: InTech, 2011:397-424.
[3]	ZHU L, LI Zh J, YU L L, et al. Research progress of carbon nanotube/polymer composite materials [J]. Science & Technology in Chemical Industry, 2009, 17(1):71-75(in Chinese).
[4]	FOGDEN S, WERDEJO R, COTTAM B, et al. Purification of single walled carbon nanotubes: The problem with oxidation debris [J]. Chemical Physics Letters, 2008, 460(1/3):162-167.
[5]	DU Y Q, SHEN Z C. Research progress of nonlinear optical limiting materials [J]. Laser Technology, 2009, 33(4): 351-354(in Chinese).
[6]	CHEN Y C, RARAVIKAR N R, SCHADLER L S, et al. Ultrafast optical switching properties of single-wall carbon nanotube polymer composites at 1.55μm [J]. Applied Physics Letters, 2002, 81(6):975-977.
[7]	LIU L, ZHAO X, ZHENG Z, et al. Carbon nanotube composite material and their applications in optical communications [J]. Optical Communication Technology, 2009, 1(6):47-50.
[8]	ZHU P, SANG M, WANG X L, et al. Research on nonlinear characteristics of SWCNT film by z-scan method measurement [J]. Laser & Optoelectronics Progress, 2012(9):091202(in Chinese).
[9]	QIN C X, QIN Z Z. The synthesis of polyimide and its film's preparation [J]. Synthetic Technology and Application, 2005, 20(2): 8-10(in Chinese).
[10]	GAN P, GU M, LI Q, et al. Third-order non-linear optical properties of tellurium-based composite films [J]. Journal of Inorganic Materials, 2011, 26(3): 295-299(in Chinese).
[11]	CHEN G X, LU H M, CHEN Y, et al. Optical fiber communication technology infrastructure [M]. Beijing: Higher Education Press, 2010:96-97(in Chinese).
[12]	SHEIK-BAHAE M, SAID A A, WEI T H, et al. Sensitive measurement of optical nonlinearities using a single beam [J]. IEEE Journal of Quantum Electronics, 1990, 26(4): 760-769.
[13]	LI L, LIU B, CHEN G R, et al. Synthesis and nonlinear optical properties of C60 derivative by sorbate [J]. Laser Technology, 2012, 36(3): 330-333(in Chinese).
[14]	SUN Q. Investigation on linear and nonlinear optical characteristics of two organic π-electron conjugated compound composite films[D]. Ji'nan: Shandong University,2010:25-27(in Chinese).
[15]	MENG X Y. Photoluminescence and nonlinear optical study of diluted magnetic semiconductor (GaMn)N[D]. Shanghai: Shanghai Jiaotong University, 2009:50-51(in Chinese).
[16]	WANG Z P. Nonlinear optical absorption study of indium nitride thin film[D]. Shanghai: Shanghai Jiaotong University,2010:41-42(in Chinese).
[17]	HE W Q. Study of the nonlinear optical properties in ZnTe and InN semiconductor[D]. Shanghai: Shanghai Jiaotong University, 2007:16-17(in Chinese).
[18]	ZHU P, SANG M, WANG X L, et al.A passive mode-locking pulse fiber laser based on single-walled carbon nanotube saturable absorber[J].Journal of Optoelectronics·Laser,2012, 23(9):1686-1690(in Chinese).

[1]	冯岩 , 林静 , 丁迎春 . 聚苯胺-多壁碳纳米管掺杂聚乙烯醇的z扫描研究. 激光技术, 2008, 32(6): 598-600.
[2]	冯林 , 王彦玲 , 任诠 , 张光辉 , 杨洪亮 , 孙香冰 . 一种新型dmit盐的三阶非线性光学性质研究. 激光技术, 2006, 30(5): 469-470,475.
[3]	张鹏飞 , 石旭刚 . 3种配合物的非线性光学性能与分子结构的关系. 激光技术, 2011, 35(1): 79-81. doi: 10.3969/j.issn.1001-3806.2011.01.022
[4]	张鹏飞 , 徐咏梅 , 郑发泰 , 杨扬 . 一种新型金属有机化合物的非线性光学特性研究. 激光技术, 2006, 30(2): 155-157.
[5]	李丽 , 刘冰 , 陈改荣 , 刘书芝 , 唐光诗 . 山梨酸酯类C60衍生物的合成及非线性光学性质. 激光技术, 2012, 36(3): 330-333,345.
[6]	闫斌 , 吴福全 , 郝殿中 , 张旭 , 毕佳 , 郑萌萌 . λ/4光学薄膜相位延迟器的温度特性. 激光技术, 2008, 32(2): 215-217.
[7]	陈俊领 , 段国平 , 黄明举 . 激光能量对沉积纳米Si薄膜晶粒尺寸的影响. 激光技术, 2012, 36(3): 322-325.
[8]	王建国 , 贺洪波 , 邵建达 , 范正修 . 光波在具有柱状结构的双折射薄膜中的传输特性. 激光技术, 2005, 29(6): 601-603,607.
[9]	唐帆斌 , 肖峻 , 马孜 . TiO2薄膜的宽光谱特性椭偏法研究. 激光技术, 2015, 39(6): 776-779. doi: 10.7510/jgjs.issn.1001-3806.2015.06.009
[10]	齐瑞云 , 吴福全 , 郝殿中 , 王庆 , 吴闻迪 . 退火温度对HfO2薄膜应力和光学特性的影响. 激光技术, 2011, 35(2): 182-184,188. doi: 10.3969/j.issn.1001-3806.2011.02.011
[11]	任豪 , 曾群 , 庞振华 , 周应恒 , 梁锡辉 . 电子束蒸发制备掺钕钇铝石榴石薄膜特性研究. 激光技术, 2012, 36(4): 450-452. doi: 10.3969/j.issn.1001-806.2012.04.005
[12]	时光 , 梅林 , 高劲松 , 张立超 , 张玲花 . 离子束溅射、热舟和电子束法制备深紫外LaF3薄膜. 激光技术, 2013, 37(5): 592-595. doi: 10.7510/jgjs.issn.1001-3806.2013.05.007
[13]	许彬 , 李斌成 , 高椿明 , 王强 , 郭小红 , 孙启明 . 真空环境下低损耗高反射光学元件性能退化特性. 激光技术, 2020, 44(6): 768-772. doi: 10.7510/jgjs.issn.1001-3806.2020.06.021
[14]	霍艳丽 , 李少兰 , 马自侠 . 溶液浓度对ZnO纳米棒形貌和发光的影响. 激光技术, 2012, 36(6): 776-779. doi: 10.3969/j.issn.1001-3806.2012.06.016
[15]	马自侠 , 李清山 , 张立春 , 赵风周 , 曲崇 , 霍艳丽 . 生长时间对氧化锌纳米棒发光性能的影响. 激光技术, 2012, 36(4): 501-503. doi: 10.3969/j.issn.1001-806.2012.04.016
[16]	梁德春 , 李清山 , 孙方华 , 李新坤 , 宗磊 . 光电探测器结构对光响应特性的影响. 激光技术, 2009, 33(2): 159-161,216.
[17]	郑萌萌 , 吴福全 , 刘在国 , 张立春 , 李清山 , 田建祥 . 阳极氧化铝膜的偏振光谱特性研究. 激光技术, 2008, 32(2): 116-118,121.
[18]	王丽丽 . 入射角对含钴氧化铝膜红外偏振光谱特性研究. 激光技术, 2011, 35(6): 773-774,832. doi: 10.3969/j.issn.1001-3806.2011.06.013
[19]	王成 , 马莹 , 张贵彦 , 肖孟超 , 甘志宏 , 缪同群 , 钱龙生 . 薄膜应力激光测量方法分析. 激光技术, 2005, 29(1): 98-100.
[20]	李玉瑶 , 王菲 , 孙同同 . 薄膜激光损伤阈值标定技术. 激光技术, 2021, 45(6): 729-734. doi: 10.7510/jgjs.issn.1001-3806.2021.06.009

点击查看大图

计量

文章访问数: 3302
HTML全文浏览量: 880
PDF下载量: 739
被引次数: 0

姓名
邮箱
手机号码
标题
留言内容
验证码

留言板

单壁碳纳米管薄膜制备及其光学特性研究

作者简介: 宋秋艳（1986- ），女，博士研究生，主要从事非线性光学材料方面的研究。.

通讯作者: 陈根祥, gxchen_bjtu@163.com ;

Preparation of single-walled carbon nanotube film and its optical property

Corresponding author: CHEN Genxiang, gxchen_bjtu@163.com ;

计量

单壁碳纳米管薄膜制备及其光学特性研究

通讯作者: 陈根祥, gxchen_bjtu@163.com;

作者简介: 宋秋艳（1986- ），女，博士研究生，主要从事非线性光学材料方面的研究。

English Abstract

Preparation of single-walled carbon nanotube film and its optical property

Corresponding author: CHEN Genxiang, gxchen_bjtu@163.com

全文HTML

目录

留言板

单壁碳纳米管薄膜制备及其光学特性研究

作者简介: 宋秋艳（1986- ），女，博士研究生，主要从事非线性光学材料方面的研究。.

通讯作者: 陈根祥, gxchen_bjtu@163.com ;

Preparation of single-walled carbon nanotube film and its optical property

Corresponding author: CHEN Genxiang, gxchen_bjtu@163.com ;

计量

出版历程

单壁碳纳米管薄膜制备及其光学特性研究

通讯作者: 陈根祥, gxchen_bjtu@163.com;

作者简介: 宋秋艳（1986- ），女，博士研究生，主要从事非线性光学材料方面的研究。

English Abstract

Preparation of single-walled carbon nanotube film and its optical property

Corresponding author: CHEN Genxiang, gxchen_bjtu@163.com

全文HTML

目录